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RAS Earth ScienceГеохимия Geochemistry International

  • ISSN (Print) 0016-7525
  • ISSN (Online) 3034-4956

PHOSPHATES IN THE IMPACT ASSOCIATIONS OF THE CHELYABINSK METEORITE

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PII
S3034495625090023-1
DOI
10.7868/S3034495625090023
Publication type
Article
Status
Published
Authors
V.V. Sharygin
  • Affiliation:
    V.S. Sobolev Institute of Geology and Mineralogy SB RAS
    Ural Federal University, Institute of Physics and Technology, Extraterra Consortium
Volume/ Edition
Volume 70 / Issue number 9
Pages
692-715
Abstract
Na-Fe- and Na-Ca-Mg-Fe-phosphates were found in the impact melt associations of the Chelyabinsk meteorite (Chebarkul fragment). They drastically differ in composition from phosphates of the initial chondrite (chlorapatite, merrillite). Chladniite NaCaMgFeMn(PO) and merrillite-like phase NaCaMgFeMn(PO) were observed in silicate part in quenched interstitial groundmass between olivine grains; merrillite and chlorapatite are rare here. The spongy metal-sulfide aggregate from large voids and metal-sulfide blebs in silicate part contain Na-Fe-phosphate globules. They consist of sarcopside and graftonite (Fe, Mn)(PO), galileiite Na(Fe, Mn)(PO), xenophyllite Na(Fe, Mn)(PO) and unidentified Na-Fe-phosphate Na(Fe, Mn)(PO), sometimes chromite-2. Dendritic-skeletal growth of crystals, evidencing about very rapid quenching, is clearly fixed in all associations of the impact melt (silicate part, vugs, metal-sulfide aggregate, metal-sulfide blebs, and phosphate globules). The following crystallization sequence is revealed in the Na-Fe-phosphate globules: chromite-2 → sarcopside/ graftonite → galileiite → xenophyllite. It is suggested that their formation was due to separation of Na-Fe-phosphate liquid from homogenous Na-P-Cr-O-dopped Fe-Ni-metal-sulfide melt. Crystallization of Na-Ca-Mg-Fe-phosphates occurred without participation of any liquation processes; and directly from silicate melt. The paper provides data on chemical composition and Raman spectroscopy for all studied phosphates, as well as for the key minerals of the impact melt associations of the Chelyabinsk meteorite.
Keywords
саркопсид графтонит галлюнит ксенофиллит хладниит фосфатные глобулы Fe-Ni-металл троилит импактный расплав метеорит Челябинск
Date of publication
30.04.2025
Year of publication
2025
Number of purchasers
0
Views
30

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