RAS Earth ScienceГеохимия Geochemistry International

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  • ISSN (Online) 3034-4956

Standard thermodynamic properties of Ag3Sn (shosanbetsuite): EMF data

PII
S0016752525020042-1
DOI
10.31857/S0016752525020042
Publication type
Article
Status
Published
Authors
Volume/ Edition
Volume 70 / Issue number 2
Pages
158-164
Abstract
Thermodynamic properties of shosanbetsuite (Ag3Sn) are first determined in the Ag–Sn system in a galvanic cell (–) Pt | Gr | Ag | RbAg4I5 | Ag3Sn, Sn | Gr | Pt (+) within the temperature range of 327–427 K in vacuum. Analysis of the data makes it possible to calculate the standard (298.15 K, 105 Pa) ΔfG0, ΔfH0, and S0 of Ag3Sn: –21238, –18763 J mol–1, and 187.5 J K–1 mol–1, respectively.
Keywords
Ag–Sn Ag3Sn ЭДС-метод шосанбецуит
Date of publication
16.09.2025
Year of publication
2025
Number of purchasers
0
Views
6

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