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ОНЗ Геохимия Geochemistry International

  • ISSN (Print) 0016-7525
  • ISSN (Online) 3034-4956

ГАЛОГЕНЫ (F, Cl) В ПРИРОДНЫХ АЛМАЗАХ: ИССЛЕДОВАНИЕ С ПОМОЩЬЮ ВТОРИЧНО-ИОННОЙ МАСС-СПЕКТРОМЕТРИИ (ВИМС)

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Код статьи
S3034495625100012-1
DOI
10.7868/S3034495625100012
Тип публикации
Статья
Статус публикации
Опубликовано
Авторы
Каминский Ф.В.
  • Аффилиация: Институт геохимии и аналитической химии им. В.И. Вернадского РАН
Бер Б.Я.
  • Аффилиация: ФГИ им. А.Ф. Иоффе
Казанцев Д.Ю.
  • Аффилиация: ФГИ им. А.Ф. Иоффе
Шилобреева С.Н.
  • Аффилиация: Институт геохимии и аналитической химии им. В.И. Вернадского РАН
Токарев М.В.
  • Аффилиация: ФГИ им. А.Ф. Иоффе
Том/ Выпуск
Том 70 / Номер выпуска 10
Страницы
785-796
Аннотация
Галогены имеют важное значение в мантийной петрологии, однако до сих пор их содержания в одном из важнейших глубинных минералов – алмазе оставались неизвестными. В данной работе впервые определены концентрации фтора и хлора в природных алмазах из кимберлитовых трубок, силлов и россыпей Бразилии и Венесуэлы с помощью метода динамической вторично-ионной масс-спектрометрии (ВИМС) и использованием ионно-имплантированных образцов сравнения. Концентрации фтора в исследованных алмазах варьируют от 0.018 ат. ppm до 0.036 ат. ppm (3.2–6.3 × 10 ат/см); концентрации хлора близки: от 0.014 ат. ppm до 0.034 ат. ppm (2.4–4.5 × 10 ат/см). По всей видимости, F и Cl связаны с микровключениями в алмазе, хотя нельзя исключать их вхождение в решетку алмаза. Источники галогенов в алмазах разнообразны. Часть F и Cl являются ювенильными, унаследованными от их первичных концентраций в мантии. Другая часть имеет своим источником мантийный резервуар, образованный за счет субдуцированного осадочного материала. Отношение F/Cl в изученных алмазах (1.00–1.82) аналогично отношениям F/Cl в кимберлитах (0.38–1.68). Оно отличается от оценок для мантии Земли (0.62–0.68) и ближе к величинам в энстатитовых хондритах (1.16–2.77).
Ключевые слова
галогены фтор хлор алмаз ВИМС энстатитовый хондрит
Дата публикации
22.05.2025
Год выхода
2025
Всего подписок
0
Всего просмотров
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Библиография

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